A remembrance
of John Hulm
Dick Blaugher, January 2004.
I first met John in the fall of 1957 when
he was manager of the "Superconductivity" department
at the Westinghouse Research Laboratory in Churchill. He interviewed
me for a job with his group that I was fortunate to obtain and
joined the labs in November of 1957. Since that time, over the
years, we have always maintained a strong relationship both
as a colleague and friend and I have personally benefited and
enjoyed this long association. I could go on and on with numerous
stories about John and his scientific contributions and his
many "other" sides but time would not allow this.
You might not know this but John has already provided us with
an excellent "autobiography" of his scientific career
that covers the period from his high school education, higher
education at Cambridge University,
and his scientific activities and colleagues up to 1982. This
after dinner talk was presented at the 1982 Applied Superconductivity
Conference and was published in the IEEE Trans. on Magnetics, Volume Mag-19,
pp 161-166. I have read and reread this excellent
talk on many an occasion and have always been fascinated and
amused with the description of his career. In his talk, John
identified almost all of the key scientists and close friends
he knew that impacted his own career and thinking during that
period. I remember sitting at the table in Knoxville listening to John's talk and one of our mutual friends, Bob
Hein, leaned over and said, "You are honored, John mentioned
your name". I indeed was honored because I recognized it
was certainly a tribute that I highly appreciated. John's reference
was to the work we did on studying the superconducting transition
metal alloys. I would like to believe, partly because I was
heavily involved, that this was the most important work we ever
did. These transition metal alloys turned out, with further
development, to be possibly the most important superconductors
for magnets and power applications due to their low cost and
ability to carry high currents in high magnetic fields.
None of you could possibly believe how the
research on the most important alloy Nb-Ti was eventually focused.
John burst into the lab one afternoon, walked over to the chalk
board, turned around, and stated that we had to study the Nb-Ti
system. I said, why, we have already studied Ti-V, Nb-Zr, and Nb-Hf
that are all very similar. Because, John answered after going
back to the chalk board and diagramming the alloy combinations
we had studied, "With Nb-Ti, we would have, God rest the
Queen, the Union Jack". Needless to say with that overwhelming
argument we went on to study Nb-Ti that just happened to be
the most important commercial superconductor of all the transition
metal alloys. Such was the persona of John, an excellent scientist,
an exceptional manager and administrator, and most important
a person who enjoyed life and took pleasure with his many associates
and activities. We have truly lost one of the great scientists
in the field of superconductivity and I personally will forever
be touched by the privilege of his friendship and association.
John
Hulm — Scientist and Friend
A
remembrance, Ted Geballe, January 2004.
I first really got to know John during a sudden blizzard in ~1954
while he and Joan were entertaining some of us at their home during
a March meeting of the American Physical Society in Pittsburgh. What could have been a logistical nightmare
was turned into, in John's words, "a jolly good time."
John then, and in the scientific and social adventures I shared
with him until these last years, had a wonderful knack of being
able to enjoy his science and the social life that went with it.
Even when things were not going well, his humor and wit were irrepressible.
He was more than a valued colleague; he was a friend who made
life exciting and fun.
One of John's important contributions was the discovery of superconductivity
in the compound of vanadium and silicon (V3Si) made
with his student Hardy when he was at the University of Chicago.
This opened a rich new field of superconductivity. Clarence
Zener induced John to join the potent group of young scientists,
which Zener attracted to Westinghouse Research. At about the
same time Bernd Matthias, with whom John had been working closely
at Chicago, moved on to Bell Labs, and continued actively
in the same field. I joined forces with Bernd soon thereafter.
A period of exciting new discoveries both at Westinghouse and
at Bell followed. It is a tribute to John and his sense of fair play,
that what might have been an unfriendly rivalry was the opposite--
it was a warm, friendly and productive competition, which ignored
or circumvented corporate guidelines as helpful unpublished
results traveled back and forth.
I recall one memorable investigation John instigated with the
motive of testing Matthias' conjecture that the very successful
theory of superconductivity discovered by Bardeen, Cooper and
Schrieffer (BCS) in 1957 was inadequate to explain superconductivity
in transition metals-those metals where the conduction electrons
come from the atomic d-shells. Studies at Westinghouse and Bell had shown that superconductivity seemed
to disappear in certain ranges of composition of transition
metal alloys in a manner at variance with the prediction of
BCS. We jointly investigated properties in this range and found,
initially to our dismay, that the BCS prediction was correct.
John's open mind and lack of ego made it easy for him to accept
and enjoy finding out that BCS was a correct theory over a much
wider range of materials than we had expected. It was a good
lesson for me.
John's scientific achievements are too numerous
to dwell on here. He pioneered in opening the field of semiconducting
superconductors, a still active field. His investigations of
transition metal alloys formed the body of knowledge needed
for the construction of superconducting magnets, which are an
essential component of the widely used nuclear magnetic resonance
imaging (MRI) systems. He led the group at Westinghouse that
made important advances made in developing superconducting magnet
technology. The many MRI scans that John must have had after
his stroke, in some wry prophetic sense, are the coming back
of some bread that he cast upon the water. Unfortunately the
further research needed to develop techniques for restoring
damaged nerves is yet to be done.
It was always fun to travel with John. His
knowledge of history-particularly English history and his classical
education provided a constant supply of interesting facts, witticisms
and wry humor. He was a loyal American with roots that extended
firmly back to his English/Cambridge upbringing. He had a passion
for railroads probably dating from his childhood days when his
father worked for the British rail system. These roots proved
to be of practical value to me when I met him at his Auntie's
house in London when he was Scientific Attaché to the U.S.
Embassy. We were headed to a visit to a national laboratory
in Germany when suddenly I remembered that I had left my passport in
Cambridge. John, his father's son, called the British railways and arranged
for Frances, my wife, to hand the passport over to the conductor
on the next train from Cambridge to London where
the conductor handed it to us in time make our flight to the
continent.
After I left Bell to go to Stanford our relationship continued as strong as
ever. We jointly wrote papers and organized meetings. John became
research director at Westinghouse. I was called in as a consultant
for several years. It was a treat to stay with the Hulms, and
enjoy Joan's hospitality and to see the growing and active children.
I cannot forget one warm summer night when we sat outdoors consuming
generous portions of a huge wheel of Stilton cheese that John
had especially imported, with beer, and lots discussion on the
latest books he had read, and which reflected his fiscal conservatism.
John was highly respected for his scientific
wisdom and his administrative fairness and honesty. These attributes
along with his clear-headed thinking were recognized by the
Westinghouse executives who appointed him the Chief Scientist
of the laboratory. John lives on as an unforgettable human being
in my mind and I would guess in the minds of many. Alas, those
glory days of research at Westinghouse with outstanding scientists
gathered by Zener and Condon and others, and continued under
Chief Scientist John Hulm, live on only in memory. I could say
the equivalent things about Bell Labs as well. I am grateful
that he, and I too, were there during those golden days.
Superconductivity
Research In The Good Old Days
J.
K. Hulm
A
talk given at the banquet of the Applied Superconductivity Conference,
Knoxville,
Tennessee,
December 1, 1982.
One of the most profound statements I ever
heard was made by Sam Goldwyn, the movie producer, who said,
"I drink to make my friends more interesting." I'm
counting on the Goldwyn effect to get me through this evening.
If you should happen to be stone cold sober, it might be best
to leave right now. I won't be offended. Just don't plan on
working for Westinghouse in the near future.
I want to thank our program chairman [David
Larbalestier] for those kind introductory remarks. I think I
need equal time to tell my side of the story.
|
ASC'82,
Knoxville TN
Left
to right, David Larbalestier, John Hulm and Richard Blaugher
|
One day in 1975, I was sitting inmy office
in the American Embassy in Grosvenor Square, London, thinking great diplomatic thoughts, when
the phone rang and a booming voice came on the line, my old
friend Roger Boom, from Wisconsin. Roger said, "Wake up, John, it's
time you did something for the taxpayers. I've got this great
English superconducting materials guy lined up for a job at
our place, but the State Dept. is delaying his visa. Can't you
do something?" I said, "What's his name?" Roger
said, "Larbalestier." I said, "Are you sure you've
got the right country?" Roger said, "Yes, of course
I am — he works at Harwell and I need your help, it's holding
up all our projects."
Well, it was fortuitous that being an ex-immigrant,
I had already established my own immigration policy for the
U.S. It has always struck me as being ludicrous that we have at
least 10 million illegal aliens in the United States
and yet in recent years we make it difficult for outstanding
scientists and engineers to come here. The official policy is
enforced by erecting paperwork barriers which produce endless
delays in processing the visa. Well, I applied my superconducting
knowledge to short-circuit this process, plus a little hospitality
to members of the visa section, and David was one of several
outstanding people whose visas got speeded up. It was probably
the most important thing I did in the diplomatic service. I
became even more convinced of that when I met David's charming
wife later on. I want to assure you that they are both here
on a completely legal basis.
Having been program chairman of the 1972
Applied Superconductivity Conference, I know that it's a lot
of hard work. Therefore I'd like to personally thank David Larbalestier
for arranging an outstanding technical program for the 1982
conference, and I would like it very much if you would join
me for a moment to thank him.
It seems to me that the greatest burden
of all has fallen upon our conference chairman, namely, Martin
Lubell.
Perhaps many of you are not aware that Martin
worked for an extended period at the Westinghouse Research Laboratories,
and, surprisingly, emerged with a completely undamaged intellect.
I suspect that he does not know that we at Westinghouse hold
him up as an example as one of our more distinguished alumni.
What we taught him at Westinghouse about spending large sums
of money on superconducting magnet development proved to be
but a prelude to the virtuoso performance which he has exhibited
since he has progressed towards the senior management levels
of Oak Ridge.
But seriously, Martin has had a distinguished career
in the science and technology of superconducting magnets. He
has also worked very hard on the organization of this conference.
I think it would be a nice gesture to offer him a vote of thanks
at this point for his excellent work as chairman of the conference.
Would you please join me in doing that?
I cannot resist the temptation to reveal a further piece
of data about the Lubell family. Probably a few of you know
that Martin's charming wife, Bernie, who is one of the organizers
of the guest program, is also a Westinghouse graduate. As a
matter of fact, Bernie was my secretary for about four years
before I gave her permission to marry Martin. She was a great
secretary, absolutely fantastic. As a matter of fact, she ran
the cryogenics group with an iron hand, leaving me free to mess
around in the lab all day. It was a sad day when this ideal
arrangement ended, but I figured Martin's need was greater than
mine and after all, man does not live by superconductivity alone.
Now when Martin called me in the summer and asked me
to give this speech, he suggested that I talk about earlier
days in superconductivity research and, in particular, about
some of the famous people I've known, such as Bernd Matthias.
I thought it would be fun to give such a talk. In the past I
have given chiefly technical talks, but this is getting increasingly
difficult to do, because I became a research administrator several
years ago, and I have to worry more about money and personnel
than about real technical details of the research. So I thought,
well, I'll give it a try.
People often say that it's O.K. to be smart, but it's
much better to be lucky. I think this certainly applies to my
career. I was fortunate in many respects.
In the first place, I entered superconductivity when
the field was a relatively small but exciting area of pure science,
and when there were some excellent opportunities for basic discoveries.
Furthermore, I have witnessed the fascinating progress of the
field from pure science to advanced technology. As I stood in
the Large Coil Test Facility at Oak Ridge last
Monday, I thought to myself, "Who could have forecast such
an amazing engineering development, even thirty years ago?"
In the language of the advertising world, "We've come a
long way, baby" — and we really have. And most exciting,
the new NMR scanners are opening up an entirely new field of
applications for superconductors. I'm delighted for all our
friends in the small, struggling superconductor companies. Hopefully
many of them will greatly benefit from this new development
and will be recompensed for their efforts as entrepreneurs.
The second respect in which I believe my luck was phenomenal
is that, with hardly any forethought, but more or less by pure
blind chance, I managed to collide with a series of brilliant
men at just the right time in my own development so that I could
not only benefit from their teachings but also be turned into
new directions which proved to be quite important.
It is in this second category that I will speak tonight.
The only way that I know to handle this is by a more or less
personal, autobiographical approach, so perhaps my talk should
really have been entitled, "My life with superconductors
and superpeople."
I got into superconductivity in the first place due
to the teachings of two men, David Shoenberg, of whom many people
here will know, and George Arthur Millward, who I am quite sure
no one in this audience except my wife, Joan, will have ever
heard of.
I grew up in a small coastal town near the northern
industrial belt of England during the great depression. My father was a modestly
paid railroad worker. At least he had a regular job, which was
not true for most of our relations. In the thirties our house
was a regular stop-over place for destitute friends and relatives.
I was very fortunate in two respects. First, my parents understood
the value of education, which they, themselves, had been deprived
of by economic circumstances. They were determined that I would
not miss my opportunity. Second, I went to a first-rate high
school headed by an exceptional educator, George Arthur Millward.
G. A. Millward stood in fourteenth place on the mathematical
first class honors list at Cambridge University in 1912, the year in which Sir Arthur Eddington, the
future cosmologist, was first or senior wrangler. I'll spell
that for those unfamiliar with the term - W-R-A-N-G-L-E-R. If you look up the word WRANGLER in the International edition
of Webster's Dictionary you will find three definitions:
FIRST: An angry or bickering disputant or argumentative
person.
SECOND: One who obtains first class honors in the mathematical tripos
at Cambridge University.
THIRD: A HORSE WRANGLER or COWBOY.
The common thread in these definitions seems to be the
word ARGUMENT. Apparently in ancient days the Cambridge mathematicians
used to have a public argument with each other in order to determine
the wranglers' pecking order. I don't know exactly how it worked,
but it sounds like more fun than written examinations. Incidentally,
the word TRIPOS comes from the Greek for a three-legged stool,
which is what the early mathematicians are supposed to have
sat upon while they conducted the wrangle. In the case of the
cowboy, I suppose that his argument was with the horse, or was
it with the cows? I don't know.
So, George Arthur Millward was fourteenth wrangler in
1912. He was 6 foot 4 inches tall and in 1915 was heavy-weight
boxing champion of the British Navy. Fortunately for me, he
survived the battle of Jutland, and
in 1919 he became the founding headmaster of our local high
school. He was known as the BOSS, and kept discipline in the
school with a large bamboo stick. For small boys, one stroke
from that stick produced a NUMB POSTERIOR for the best part
of a week, plus a firm resolve never again to incur the BOSS'S
wrath.
You might think that this man sounds like a BULLY. Well,
he was certainly a strict disciplinarian, but he was much more
complex than that. He went out of his way to stimulate any kind
of schoolboy talent with special classes; he personally gave
extra mathematics coaching to small groups of students year
after year. At my last count, three fellows of the BRITISH ROYAL
SOCIETY and three members of the U.S. National Academy of Engineering
originated from that small high school in that small town, an
achievement far out of proportion to the size of the local population.
One of the graduates is currently president of the Bell Telephone
Laboratories. I think a lot of credit is due to the fourteenth
wrangler of 1912, George Arthur Millward.
This little story is only relevant to the fact that
I'm absolutely sure that if it hadn't been for that little-known
but remarkable man, I wouldn't be standing here tonight. I suspect
that the majority of scientists and engineers in this room can
think of a teacher whose influence was crucial at some point
in life. Well, Christmas is almost upon us, and it's a good
time to recollect those who inspired you. If they are still
alive, why don't you make a note to go see, phone, or send a
card to say you were thinking of them and what a difference
they made to your life? It would be a nice thing to do.
Well, the BOSS got me into Cambridge University
in 1941, and in my second year I met another remarkable man,
David Shoenberg. He was teaching a class on electric and magnetic
susceptibilities of materials based on VAN VLECK's famous textbook.
The term solid-state physics was not then in general use, but
David's course literally electrified me. I was absolutely intrigued
by the thought that one could calculate the properties of a
complex lump of matter from first principles. I think my future
path was decided at that point.
Graduate studies and basic research in physics at the
Cavendish Laboratory had been suspended for the duration of
the war, and Shoenberg was in fact working on proximity fuses
when not teaching. He suggested that if we both survived the
war, I might like to do graduate work with him, which I subsequently
did.
I'll spare you the details of my war memoirs. I worked
on microwave radar equipment and electronic countermeasures
for the Royal Air Force. It was very useful engineering experience,
which I believe all physicists should have quite early in life.
Well, with a little help from the United States
and the Russians, we eventually won the war, and in 1946 I got
out of the Air Force and became a graduate student at the Royal
Society Mond Laboratory, a small low temperature research lab
which was part of the Cavendish Physics Laboratory in Free
School Lane, Cambridge.
I'd like to explain how the Cavendish got into low temperature
physics. As is well known, the Cavendish was the point of origin
of much of modern physics, with the remarkable professorial
sequence represented by James Clerk Maxwell, Lord Rayleigh,
J. J. Thomson, who discovered the electron, and Ernest Rutherford,
who founded nuclear physics. In the 1920s, Lord Rutherford's
protégé was a Russian graduate student named Peter Kapitza,
who was interested in the properties of matter at very high
magnetic fields. In 1930, Kapitza managed to persuade Rutherford to get money from the MOND Nickel Company via the Royal
Society to build a high magnetic field lab which became known
as the MOND. This was a pulsed field lab, in which a large dc
generator with a flywheel was discharged through a copper magnet.
As his experiments proceeded, Kapitza thought it would
be a good idea to cool the magnets down to low temperatures
and he began to acquire cryogenic equipment. Being a very original
thinker, he wanted to operate differently from the existing
liquid helium research labs at Leiden and
Berlin, which
employed Joule-Thomson liquefiers using nitrogen, hydrogen,
and helium in cascade. So, Kapitza constructed the first expansion
engine to operate at liquid helium temperatures and thus avoided
the hydrogen cycle. I subsequently used this primitive machine
to get liquid helium for my thesis work. It was very temperamental,
but it was the forerunner of the Collins liquefier, which triggered
the great expansion of low temperature research in the U.S. in the
1950s.
Now around 1935, Kapitza went back to the U.S.S.R.,
as he did every summer, for his annual vacation. Apparently
it was suggested to him by the Soviet leaders that his services
were needed in Moscow to build
up Soviet science. He then started the famous Institute for
Physical Problems, and he didn't return to Cambridge. The Mond continued to operate under the Canadian physicist,
J. F. Alien, who had done pioneering work on superconducting
alloys with McClennan at the University of Toronto, and David Shoenberg, who was one of Kapitza's graduate
students.
Now David Shoenberg was also of Russian origin. His
parents had emigrated from Czarist Russia to England, where his father became
director of research for Electrical and Musical Industries,
a large electronics firm. In the late 1930s, David went over
to visit Kapitza in Moscow. It
was there that he wrote the first edition of his famous monograph
on superconductivity, which has served to introduce many students
to our subject. I'm sure that most of you know it.
When I entered the Mond in 1946, I shared a small lab
with another student, A. B. Pippard. Many of you will also remember
Pippard's remarkable work on the anomalous skin effect in metals.
This subsequently led to the concept of coherence length in
superconductors and was one of the scientific paths which led
to Abrikosov's theoretical discovery of type II superconductivity.
Pippard also more or less invented FERMIOLOGY, and went on to
become the Cavendish Professor himself.
It was very frustrating to be blessed with a lab-mate
like Pippard. With my own limited capacities, I seemed to find
it necessary to work at least 12 to 15 hours a day in that lab
to make even the slightest dent on my thesis problem.
It always seemed to me that Pippard achieved astounding
results with virtually no effort. He never showed up at all
before lunch time. He would come in whistling cheerfully at
about 2:30 p.m.,
turn a few valves, put in a little liquid helium, write down
a few numbers, emit a few self-congratulatory grunts, and then
announce that it was tea-time and disappear in the direction
of the Cavendish tea-room. There he would hold forth on some
abstract point of Greek mythology or some other esoteric subject
which served to illustrate the broad range covered by his remarkable
intellect.
As far as I could tell, Pippard spent his evenings giving
elegant dinners and playing Bach and Beethoven on a grand piano
in his rooms. At one time I had a theory that he sneaked back
into the lab late at night to do his experiments, but I was
never able to catch him at it. Altogether, Pippard's image was
rather terrifying to a working-class lad like myself.
I don't want to give the impression that my life was
all grind, either. Those immediate post-war summers were exceptionally
warm and beautiful and I spent a lot of time on the River Cam
with various girls, including eventually my wife, Joan, whom
I met in 1948. I became expert in the art of punting. No, I
wasn't trying to kick a ball for the local football team. I'm
referring to the age-old English sport having to do with the
propulsion of a flat-bottomed boat along the River Cam by means
of a long pole.
David Shoenberg's wife, Kate, discovered my talent for
this activity and I was pressed into service to punt the wives
and families of distinguished physicists who happened to be
visiting the Mond. In this way I got to know the wives of Werner
Heisenberg, Lars Onsager, Cornelius Gorter, Kurt Mendelssohn,
and many others. I'm sure that my subsequent progress was partly
due to this boat work.
At this time there were only two sizable low temperature
research labs in the United
Kingdom, the Mond and
our great archrival the Clarendon Lab in Oxford. The Clarendon low temperature facilities were also
built up in the 1930s when Professor Lindemann took in a number
of German refugees from the Hitler regime. This group was led
by Francis Simon, who pioneered in another useful technique
for liquefying helium by desorption from charcoal at high pressure.
Simon was external examiner for my thesis and although I was
scared stiff of him at first, this great low temperature pioneer
proved to be kind and considerate. I had several pleasant interactions
with him prior to his untimely death in the mid-1950s.
Two other senior professors at the Clarendon were Nicholas
Kurti, who pioneered in adiabatic cooling below 1 K, and Kurt
Mendelssohn, who did a lot of original work on both liquid helium
and superconductors for over 40 years and founded both our cryogenics
journal and the International Cryogenic Engineering Conference.
Mendelssohn came to Cambridge on one occasion to give
a seminar and visited the various individual laboratories in
the Mond, including mine. He seemed unusually interested in
my experiments on heat conductivity in superconductors, and
being rather wet behind the ears, I told him exactly what I
was doing and described my experimental techniques in great
detail. To this day I'm convinced that Mendelssohn immediately
went back to Oxford and
assigned a graduate student to do the identical experiments
by the same method. They ran a crash program and ultimately
beat me into print. Incidentally, that student was Jorgen Olsen,
who subsequently became professor of physics at ETH in Zurich. He and I are good friends today. I hold Olsen completely innocent of
unseemly behavior, he couldn't do it if he tried! He didn't
learn of my work until my paper on thermal conductivity eventually
came out.
Well, at the time I was really annoyed. My boss, David
Shoenberg, remonstrated gently with Mendelssohn, who merely,
said that we didn't have a monopoly on heat conductivity at
Cambridge and in any case he had
worked on the topic before the war and therefore had prior claim.
This experience taught me a lesson about the working
of professorial minds, but I have to say that subsequently I
got to know Kurt Mendelssohn very well indeed and received many
kindnesses at his hands and from his family. In retrospect,
I think that his behavior was simply governed by an unusual
competitive drive which meant no harm to anyone, and I guess
it didn't really hurt me in the long-run.
In the post-war period we had a large number of foreign
visitors to the Cavendish with a rich profusion of seminars
in constant progress. These included U.S. luminaries such as J. C. Slater, Lars Onsager, and
Linus Pauling. Sam Collins came over to tell us about his new
helium liquefier, which was going into mass production at A.
D. Little, but no one in our lab quite believed that there would
be any market whatsoever for such machines. The staff shook
their heads and said "what folly."
We also had a lot of contact with the Kamerlingh-Onnes
lab in Leiden. Professor Cornelius J. Gorter gave a lecture series
at the Mond and he invited me for a visit to Leiden in 1948. Gorter's many
contributions to physics included the two-fluid model of superconductors
and the early concept of negative interphase energy as a cause
of high field superconductivity. I would say that next to Shoenberg,
he was my father figure in low temperature physics, and we had
many interactions in later years — a wonderful man.
Now when I first entered the Mond, I didn't immediately
work on superconductors, because there was a shortage of liquid
helium. Shoenberg suggested that I do some work on ferroelectric
materials, in particular the properties of barium titanate.
At the time this was known only in ceramic form, and we wanted
to grow some single crystals to determine the exact dielectric
properties. This problem also interested Sir Lawrence Bragg,
then the head of the Cavendish. He assigned two crystallographers,
Herbert Kay and Rene Rhodes, to work on this problem in a close
collaboration with me.
One of the pleasures of working on ferroelectricity
was that I got to assist Sir Lawrence as demonstrator in a series
of lectures which he gave on cooperative phenomena at the Royal
Institution in London. I also
got to demonstrate ferroelectricity in KDP at the Royal Society
"conversazione," or evening discourses, which were
attended by many distinguished people including the then Prime
Minister, the Right Honorable Mr. Clement Attlee.
Sir Lawrence Bragg was a great crystallographer. In
his position as head of the Cavendish he followed four giant
intellects, Maxwell, Rayleigh, Thomson, and Rutherford. Posterity will hopefully remember Bragg as the man
who recognized the need for structural research on biological
molecules and started the drive towards the spiral helix and
modern bioengineering. But that's another story!
We commenced our work on barium titanate late in 1946
and we messed around for about six months trying to grow single
crystals from various molten fluxes. All we could get was black
cruddy material with high conductivity. Then one day Professor
Paul Scherrer from Zurich, of
Debye-Scherrer fame, happened to be visiting Sir Lawrence at
the Cavendish. When told of our difficulties, Scherrer remarked,
"The correct flux for barium titanate is barium chloride."
The next day we tried this recipe. Sure enough we soon
obtained clear, insulating crystals of barium titanate. We measured
their dielectric properties and Curie points and prepared a
letter for publication in Nature. At the last minute, Sir Lawrence,
a very ethical man, thought it best to check by telephone with
Scherrer on the use of his recipe. The response was "No
problem, go ahead and publish."
Well, about two weeks after our paper appeared in print
we got a rather nasty letter from one Bernd T. Matthias, also
of Zurich, stating
that we were unscrupulous pirates who had stolen his life's
work, or words to that effect. This was followed shortly by
an article by this person in Nature describing the properties
of various perovskite dielectrics, such as barium titanate,
but conspicuously omitting any reference to our earlier work.
We wrote to Matthias explaining that Scherrer had given us clearance
on publication, but he never replied to our letter.
Well, I had almost forgotten about this incident in
1949, when I arrived at the University of Chicago to take a post-doctoral fellowship at the Institute
for the Study of Metals. Joanie and I crossed the Atlantic on
a ship from Liverpool to Halifax, Nova Scotia, and then by train across Canada and
down to Chicago, all with a month-old baby. I already had the
Ph.D. degree, but I needed to get the BTA, that is, "Been
to America." Again, I didn't
know it, but I was blundering into the highest concentration
of physical intellect in North
America, including not only Enrico Fermi and Edward Teller,
but also many of the prime movers of the Manhattan project.
It seems strange, nowadays, to recall the fact that
there were relatively few low temperature research labs on the
North American continent prior to World War II. As I recall,
the prominent labs were at Toronto under
McClennan, at Yale under C.
T. Lane, at Berkeley under
Giauque, and at the National Bureau of Standards under Brickwedde.
After the war, two of Giauque's students, who had also worked
in the Manhattan project, Earl Long and Willard Stout, constructed
large (for that time) hydrogen and helium liquefiers of the
Joule-Thomson type, in the old West Stand of Stagg field at
the University of Chicago, right next door to the space where
the first nuclear pile had been operated in 1942. One of the
primary objectives was to provide concentrated proton targets
for the new synchrocyclotron which Enrico Fermi and others were
constructing on the other side of Ellis Avenue.
Well, I went to work in the old west stand in November
1949. I soon met the chairman of the physics department, Andrew
Lawson, who invited Joan and me to dinner at his house. Unbeknownst
to me, this character Matthias from Zurich had just joined the department as assistant professor
and was invited to the same dinner.
When Mary Ann Lawson introduced me to Matthias, he said,
"Hulm, Hulm, the Englishman? You can't be that blankety-blank
Englishman who stole my work?" I said, "You mean barium
chloride?" He said, "Come outside so I can kill you."
Well, to cut a long story short, I managed to persuade
him to postpone the murder until after we had eaten, by which
time he was so pleased to find someone who had a background
in ferroelectric materials that we began to plan some experiments
together.
This was another major turning point in my life. To
explain, I need to tell a little bit of the history of Bernd
Matthias: He was born in Frankfurt on Main, Germany, and was sent to Switzerland by his parents as
a young man to escape the Nazis. He studied under Scherrer at
Zurich and
had worked at both MIT and Bell Labs before he came to Chicago.
Prior to this time, he had already discovered a huge
number of new ferroelectric materials, many of which have since
proved to be of great importance for piezo-electric and electro-optical
applications, for example, lithium niobate. His forte could
be described as substitutional chemistry. He had a profound
knowledge of the periodic table, atomic and ionic sizes, crystal
structures, and an uncanny ability to predict new stable compositions.
He also knew how to make new materials, especially single crystals.
Matthias and I made a bargain. He would teach me materials
chemistry if I would teach him low temperature physics. It was
a good deal, for both of us.
I never met a man who had a more copious flow of ideas
for new materials than Bernd Matthias. He prepared new compounds
and I liquefied helium all day, and we both measured them at
night. If we got significant results, we celebrated with banana
cream pie at Gordon's, an all-night dive on 57th
Street. No results, no pie, that was the rule.
In those days we had no effective storage vessels for
liquid helium, at least not until the Wexler-type metal dewars
became readily available in the middle fifties. Liquid helium
had to be prepared just prior to each experiment.
Our lab in the old west stand had been a squash court.
It was incredibly dirty — I suspect we inherited a lot of graphite
from the pile. In summer, with the external temperatures in
the nineties, we were bathed in steam from a leaky steam line
which was part of the campus heating system. This also provided
hot water to the neighboring Argonne site and could not be shut
off even in August. All this paled into insignificance because
of the excitement of the work and the infectious enthusiasm
which Bernd generated.
Bernd had a Pontiac convertible and was always getting stopped for speeding.
He drove as he worked — speedily. He taught me the Chicago trick
of keeping a ten-dollar bill folded in with your license. The
Chicago cops
always asked for your license first, and of course, the bill
was missing when you got it back, with a caution to be more
careful. It's amazing that we didn't end up in the slammer.
Bernd also taught me to drive, by a novel technique.
He made me drive around backwards for several hours in the Soldier's
field parking lot. It really works — it makes driving forward
seem quite easy.
We worked on ferroelectrics for about a year and found
several new materials, particularly with Curie points at low
temperature. From a theoretical viewpoint, these superdielectrics
were reasonably well understood by 1950, whereas of course there
was no satisfactory theory of superconductors. In casual conversation
at lunchtime one day, Fermi remarked that superconductivity
was a more important physical frontier — so why didn't we work
on the materials aspects? Actually, Bernd and I had discussed
this frequently, but Fermi's comment gave us the necessary impetus.
Personally, I was doubtful about the usefulness of the
chemical approach. The Cambridge, Oxford, and Leiden approach was definitely to concentrate on the physical
aspects of more or less ideal superconductors such as tin, and
of course, this paid off in the isotope effect discovery and
led more or less directly to the BCS theory in 1957. The payoff
for Matthias' chemical approach was quite different — it led
eventually to high field superconductors and helped to foster
the transition of superconductivity from a basic research phenomenon
to a field with technological applications.
Despite my misgivings, we directed our research at obtaining
new materials with higher critical temperatures. Initially we
examined carbides and nitrides of the transition metals, going
over much of the ground already ploughed by Walter Meissner
and his associates at the Physikalische Technische Reichsanstalt,
in Berlin around 1930. We didn't
get anything notable at first.
In 1951 Matthias decided to quit the University
of Chicago to return to Bell Labs. He had been on leave from the
labs all along, and he was quite disappointed because he didn't
obtain tenure at Chicago that year. We continued to exchange results and ideas
by phone.
In the spring of 1952 I was working with a graduate
student, George Hardy. We decided that the carbides and nitrides
were more or less exhausted, so we moved down to suicides and
germanides in the second and third periods. We also began arc-melting
our samples. These were two very fortunate moves. Not only was
the general quality of the samples improved over our earlier
sintered materials, but we soon discovered a new high Tc
superconductor, V3Si, at 17 K. It belonged to
what was then known, erroneously, as the beta-tungsten structure;
of course this was subsequently changed to A15. I told this
news to Bernd almost immediately.
By then he had teamed up with Ted Geballe, Ernie Corenzwit,
and Seymour Geller at the Bell Laboratories. These investigators
proceeded to execute a tour-de-force in creative synthesis by
discovering about 30 new A15's, including several new high Tc
materials, most prominently Nb3Sn at 18 K, in
1954.
At Chicago Matthias and I had also begun a preliminary
study of the critical temperatures of the solid solution alloys
of the transition metals, such as niobium-titanium and niobium-zirconium,
but we had a lot of metallurgical difficulties with sintered
samples. In 1954 I moved to the Westinghouse Research Laboratories
in Pittsburgh. I was fortunate to
meet Dick Blaugher shortly thereafter. Dick and I measured all
of the nearest-neighbor body-centered cubic binary solid-solution
alloys, just in time for the age of superconducting magnets,
which was about to dawn, although we didn't know it at the time.
It was well known to most superconductivity researchers
at that time, in the fifties, that many superconducting alloys
showed zero resistance at quite high fields, well above the
normal or thermodynamic critical field. It was also a popular
belief that this anomalous high field behavior was due to small
regions of impurity or metallurgical defects. This carried with
it the additional false assumption that these high field zones
would normalize if subjected to appreciable electric currents.
During the post-war decade, several experiments were done which
should have destroyed some of these mistaken concepts regarding
high field superconductivity, but the metallurgical defect model
lingered on. For example, several investigators showed that
cold-worked niobium wire was capable of carrying a current density
exceeding 105 amperes per cm² at fields of several
kilogauss — which greatly exceeded the thermodynamic critical
field. At the University of Illinois in 1955, G. B. Yntema built a 7-kilogauss iron-cored
magnet, using cold-worked niobium wire. S. Autler constructed
similar magnets for maser applications in the late fifties.
With a similar application in mind, a group led by J. E. Kunzler
at the Bell Laboratories constructed a 15-kilogauss magnet using
molybdenum-rhenium wire, in 1959. Slowly but surely, the possibility
of high current densities and high fields became apparent.
The situation was opened up with a bang in December
1960 when Kunzler's group found that the compound Nb3Sn
would carry high electric current densities at fields approaching
10 Tesla. This breakthrough immediately started a major race
in the United States
through the summer of 1961 to construct high field superconducting
magnets. The first thing that had to be done was to make a long
length of superconducting wire — no small task at that time.
The Bell Labs scientists employed a niobium-tin mixture
in a niobium tube which was reacted after winding. There were
two other groups seriously in the race. Ted Berlincourt and
Dick Hake at Atomics International had made some elegant critical
field measurements on the solid solution alloys. They teamed
with the Wah Chang Company to obtain niobium-zirconium wire.
At Westinghouse we also fixed on niobium-zirconium, which was
made in our metallurgy department by Malcolm Frazer and R. A.
Wien. Hank Riemersma and I built and tested the coils.
The first phase of the big race came to somewhat of
a climax at a conference on high magnetic fields which took
place at MIT in the fall of 1961. The first three days of the
meeting were devoted to ordinary high field magnets, but there
was a special session on Saturday morning on the new magnets.
The big auditorium was packed and there was an expectant hush
— great results were anticipated.
Gene Kunzler spoke first, and I was second. He said
that the previous night they had run a magnet up to 68 kilogauss
for the first time. They had beaten us again by a slight margin
—we only had 60 kilogauss that week. When Gene had finished
his paper, the projectionist in the booth accidentally mixed
my slides together with Gene's and gave him the whole package.
The result was that when I called for the first slide, they
couldn't find it.
It's not a good experience to go before a large, excited
audience which is dying for information, only to be rendered
more or less helpless. The chairman began to harangue the projectionist,
who said he didn't have to take that from anybody and walked
out. After 10 agonizing minutes, Gene Kunzler happened to look
in his slide packet and discovered my missing slides. He promptly
went to the booth and ran the projector for me. In the same
session, Berlincourt, Hake, and Leslie reported field results
almost identical with ours.
Those tiny, primitive magnets were, of course, terribly
unstable and tended to damage themselves on normalization, for
reasons that are now well understood. One had to have faith
to believe that these erratic toys of the low temperature physicist
would ever be of any consequence as large engineered devices.
Well, of course, the new technological prospects did
create considerable excitement in the research community. I
acquired a whole new circle of colleagues — some started out
as competitors, but ended up as friends, as mostly happens in
our field. Many of these men are here in this room tonight and
they are the ones who made the technology grow; they helped
to understand the anatomy of the flux jump and the instabilities
of magnets and the techniques for protection of large coils.
I regret that time does not allow me to go into the
history of those first few exciting years of magnet development.
There is enough material in that story for several after-dinner
talks, which perhaps will be given at future conferences.
At Westinghouse we had our ups and downs. In the mid-60's
some of our highly paid executives decided that our work had
no future and almost eliminated our superconductivity staff.
Fortunately, enough of us survived in the woodwork to begin
a rebuilding process, and today we have a large group which
I can say is outstanding because I don't run it anymore.
After the MIT meeting the Bell Laboratories decided
not to proceed with magnet development, but they did continue
the materials research program. In the late sixties Ted Geballe
and Bernd Matthias scored another coup by achieving the first
critical temperature above 20 Kelvin, with niobium-aluminum-germanium.
I was especially pleased in 1972 when John Gavaler in our laboratory
brought the record back to Pittsburgh, with niobium-3-germanium
at 23 Kelvin, which is where things stand today.
Bernd Matthias never took much part in magnet development,
although he was certainly delighted with the rapid advance of
the technology. He did continue to discover new superconductors
and he turned out whole new families of ternary compounds which
will keep the solid-state physics community busy in detailed
investigations for many years to come.
Matthias became a professor at the University
of California, San Diego, and also worked actively with the materials group
at Los Alamos. He continued his work at the Bell Laboratories. At
times he would run a research program simultaneously at all
three locations —this became known as "telephone physics."
He was preparing to add a German laboratory to this Matthias
Bell system at the time of his death in 1980.
A month before Bernd died, we were together at the 1980
Applied Superconductivity Conference in Santa Fe. On the third day he
said, as was his wont, "I've heard all this stuff before,
let's get out of here." So we took some sandwiches and
a bottle of wine and drove up to the mountains behind Los
Alamos. As we sat on a high hill looking out over a magnificent
New Mexico vista, Bernd said, "Hey, John, when we started
out in the dirty old lab in the West Stand, did you ever think
it would turn out like it did?" I replied, "No, Bernd,
honestly, I DIDN'T think it would."